51. Du, K.; Guo, P.; Chen, Y.; Cao, Z.; Wang, Z,; Tang, W*. "Enantioselective Palladium-Catalyzed Dearomative Cyclization for Efficient Synthesis of Terpenes and Steroids".
Angew. Chem., Int. Ed. 2015, 54, 3033-3037. (hot paper). [doi]
50. Li, C.; Chen, T.; Li, B.; Xiao, G.; Tang, W*. "Efficient Syntheses of Sterically Hindered Acyclic Secondary Alkyl Arenes by Suzuki-Miyaura Cross-Couplings". Angew. Chem., Int. Ed. 2015, 54, 3792-3796. [doi]
49. Fu, W.; Nie, M.; Wang, A.; Tang, W*. "Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones". Angew. Chem., Int. Ed. 2015, 54, 2520-2524 . [doi]
48. Xu, G.; Zhao, Q.; Tang, W*. "Development of Efficient Asymmetric Suzuki-Miyaura Cross-Coupling and Applications in Synthesis".
Chin. J. Org. Chem. 2014, 34, 1919-1940 (Invited Account, Cover Paper). [doi]
47. Li, C.; Xiao, G.; Zhao, Q.; Liu, H.; Wang T.; Tang, W*. "Sterically Demanding Aryl-Alkyl Suzuki-Miyaura Coupling".
Org. Chem. Front. 2014, 1, 225-229 ( highlighted as OCF Cover Paper). [doi]
46. Xu, G.; Fu, W.; Liu, G.; Senanayake, C. H.; Tang, W*. "Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions".
J. Am. Chem. Soc. 2014, 136, 570–573( highlighted as JACS Cover Paper, by Synfacts). [doi]
45. Reeves, J. T.*; Tan, Z.; Reeves, D. C.; Song, J. J.; Han, Z. S.; Xu, Y.; Tang, W.; Yang, B.; Razavi, H.; Harcken, C.; Kuzmich, D.; Mahaney, P. E.; Lee, H.; Busacca, C. A.; Senanayake, C. H. "Development of an Enantioselective Hydrogenation Route to (S)-1-(2-(Methylsulfonyl)pyridin-4-yl)propan-1-amine".
Org. Process Res. Dev. 2014, 18, 904–911. [doi]
44. Cai, Z.; Liu, G.; Jiao, G.; Senanayake, C. H.; Tang, W*. "Practical Syntheses of N-Acetyl (E)-β-Arylenamides".
Synthesis. 2013, 45, 3355-3360. [doi]
43. Liu, G.; Xu, G.; Luo, R.; Tang, W*. "Search for Ideal P-Chiral Phosphorus Ligands for Practical Asymmetric Hydrogenation and Asymmetric Suzuki-Miyaura Coupling".
Synlett. 2013, 24, 2465-2471 ( Synpacts, invited review). [doi]
42. Li, K.; Hu, N.; Luo, R.; Yuan, W.; Tang, W*. "A Chiral Ruthenium –Monophosphine Catalyst for Asymmetric Addition of Arylboronic Acids to Aryl Aldehydes". J. Org. Chem. 2013, 78, 6350-6355 ( highlighted by Synfacts). [doi]
41. Luo, R.; Li, K.; Hu, Y.; Tang, W*. "Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Trifluoromethyl Ketones". Adv. Syn. Cat. 2013, 355, 1297-1302. [doi]
40. Liu, G.; Liu, X.; Cai, Z.; Jiao, G.; Xu, G.; Tang, W*. "Design of Phosphorus Ligands with Deep Chiral Pockets: Practical Synthesis fo Chiral β-Arylamines by Asymmetric Hydrogenation".
Angew. Chem., Int. Ed. 2013, 52, 4235-4238 ( Highlighted in Chin. J. Org. Chem.; Chemistry Portal Highlights). [doi]
39. Zhao, Q.; Li, C.; Senanayake, C. H.; Tang, W*. "An Efficient Method for Sterically Demanding Suzuki-Miyaura Coupling Reactions". Chem. Eur. J. 2013, 19, 2261-2265. [doi]
38. Li, W.*; Rodriguez, S.; Duran, A.; Sun, X.; Tang, W.*; Premasiri, A.; Wang, J.; Sidhu, K.; Patel, N. D.; Savoie, J.; Qu, B.; Lee, H.; Haddad, N.; Lorenz, J.C.; Nummy, L.; Hossain, A.; Yee, N.; Lu, B.; Senanayake, C. H. "The P-Chiral Phosphane Ligand (MeO-BIBOP) for Efficient and Practical Large-Scale Rh-Catalyzed Asymmetric Hydrogenation of N-Acetyl Enamides with High TONs". Org. Process Res. Dev. 2013, 17, 1061–1065. [doi]
37. Tang, W.; Patel, N. D.; Wei, X.*; Byrne, D.; Chitroda, A.; Narayanan, B.; Sienkiewicz, A.; Nummy, L. J.; Sarvestani, M.; Ma, S.; Grinberg, N.; Lee, H.; Kim, S.; Li, Z.; Spinelli, E.; Yang, B.; Yee, N.; Senanayake, C.H. "Synthesis of a Sodium–Hydrogen Exchange Type 1 Inhibitor: An Efficient Cu-Catalyzed Conjugated Addition of a Grignard Reagent to an Acetyl Pyridinium Salt". Org. Process Res. Dev. 2013, 17, 382–389. [doi]
36. Tang, W.*; Patel, N. D.; Xu, G.; Xu, X.; Savoie, J.; Ma, S.; Hao, M.; Keshipeddy, S.; Capacci, A. G.; Wei, X.; Zhang, Y.; Gao, J. J.; Li, W.; Rodriguez, S.; Lu, B. Z.; Yee, N. K.; Senanayake, C.H. "Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki–Miyaura Coupling Reactions".
Org. Lett. 2012, 14 , 2258–2261. [doi]
35. Tang, W.*; Wei, X.; Yee, N. K.; Patel, N.; Lee, H.; Senanayake, C.H. "A Practical Asymmetric Synthesis of Isopropyl (1R,2S)-Dehydrocoronamate".
Org. Proc. Res. Dev. 2011, 15, 1207-1211. [doi]
34. Li, W.*; Gao, J. J.; Zhang, Y.; Tang, W.; Lee, H.; Fandrick, K. R.; Lu, B.; Senanayake, C.H. "A Mild Palladium-Catalyzed Suzuki Coupling Reaction of Quinoline Carboxylates with Boronic Acid".
Adv. Syn. Cat. 2011, 353, 1671-1675. [doi]
33. Tang, W.*; Patel, N. D.; Capacci, A. G.; Wei, X.; Yee, N. K.; Senanayake, C.H. "A Facile Synthesis of N-Acetyl Enamides by Reductive Acetylation of Oximes Mediated with Ferrous Acetate:Synthesis of N-(1-(4-Bromophenyl)vinyl)acetamide".
Org. Syn. 2013, 90, 62-73. [doi]
32.Tang, W.*; Keshipeddy, S.; Zhang, Y.; Wei, X.;Savoie, J.; Patel, N. D.; Yee, N. K.; Senanayake, C.H. "Efficient Monophosphorus Ligands for Palladium-Catalyzed Miyaura Borylation".
Org. Lett. 2011, 13, 1366-1369. [doi]
31. Rodriguez, S.*; Qu, B.; Haddad, N.; Reeves, D.; Tang, W.*; Krishnamurthy, D.; Senanayake, C.H. "Dihydrobenzooxaphosphole-Based Monophosphorus Ligands for Palladium-Catalyzed Amination Reactions".
Adv. Syn. Cat. 2011, 353, 533-537. [doi]
30. Tang, W.*; Wei, X.; Li, W.; White, A.; Patel, N. D.; Savoie, J.; Gao, J. J.' Rodriguez, S.; Qu, B.; Haddad, N.; Lu, B. Z.; Krishnamurthy, D.; Yee, N. K.; Senanayake, C.H. "A General and Special Catalyst for Suzuki-Miyaura Coupling Processes".
Angew. Chem., Int. Ed. 2010, 49, 5879-5883. ( Highlighted as "Synfact of the month" by Synfacts in Nov. 2010). [doi]
29. Fandrick, D. R.*; Fandrick, K. R.; Reeves, J. T.; Tan, Z.; Tang, W.; Capacci, A. G.; Rodriguez, S.; Song, J. J.; Lee, H.; Yee, N. K.; Senanayake, C.H. "Copper Catalyzed Asymmetric Propargylation of Aldehydes".
J. Am. Chem. Soc. 2010, 132, 7600-7601. [doi]
28. Tang, W.*; Capacci, A. G.; White, A.; Ma S.; Rodriguez, S.; Qu, B.; Savoie, J.; Patel, N.; Wei, X.; Haddad, N.; Grinberg, N.; Yee, N. K.; Krishnamurthy, D.; Senanayake, C. H. "Novel and Efficient Chiral Bisphosphorus Ligands for Rhodium-Catalyzed Asymmetric Hydrogenation".
Org. Lett. 2010, 12, 1104-1107. ( Highlighted by Synfacts). [doi]
27. Tang, W.*; Qu, B.; Capacci, A.; Rodriguez, S.; Wei, X.; Haddad, N.; Narayanan, B.; Ma S.; Grinberg, N.; Yee, N. K.; Senanayake, C. H. "Novel, Tunable, and Efficient Chiral Bisdihydrobenzooxaphosphole Ligands for Asymmetric Hydrogenation".
Org. Lett. 2010, 12, 176-179. [doi]
26. Ma S.; Shen, S.; Haddad, N.; Tang, W.; Wang, J.; Lee, H.; Yee, N.; Senanayake, C. H.; Grinberg, N.* "Chromatographic and Spectroscopic Studies on the Chiral Recognition of Sulfated beta-Cyclodextrin as Chiral Mobile Phase Additive".
J. Chromatography A, 2009, 1216, 1232-1240. [doi]
25. Tang, W.*; Capacci, A.; Sarvestani, M.; Wei, X.; Yee, N. K.; Senanayake, C. H. "A Facile and Practical Synthesis of N-Acetyl Enamides".
J. Org. Chem. 2009, 74, 9528-9530. [doi]
24. Tang, W.*; Sarvestani, M.; Wei, X.; Patel, N.; Narayanan, B.; Nummy, L. J.; Byrne, D.; Lee, H.; Yee, N.; Senanayake, C. H. "Formation of 2-Trifluoromethylphenyl Grignard Reagent via Magnesium-Halogen exchange: Process Safety Evaluation and Concentration Effect".
Org. Proc. Res. Dev. 2009, 13, 1426-1430. [doi]
23. Han, Z.*; Song, J. J.; Yee, N. K.; Xu, Y.; Tang, W.; Reeves, J. T.; Tan, Z.; Wang, X.; Lu, B.; Krishnamurthy, D.; Senanayake, C. H. "Development of a Preparative-Scale Asymmetric Synthesis of (R)-p-Tolyl Methyl Sulfoxide for Use in a One-Pot Synthesis of a Drug Intermediate Containing a Trifluoromethyl-Substituted Alcohol Functionality".
Org. Proc. Res. Dev. 2007, 11, 605-608. [doi]
Publications during graduate and postdoctoral research:
22. Ito, E.; Frederick, M. O.; Koftis, T. V.; Tang, W.; Petrovic, G.; Ling, T.; Nicolaou, K. C.* "Structure toxicity relationships of synthetic azaspiracid-1 and analogs in mice". Harmful Algae 2006, 5, 586-591.
21. Nicolaou, K. C.*; Koftis, T. V.; Vyskocil, S.; Petrovic, G.; Tang, W.; Frederick, M. O.; Chen, D. Y.; Li, Y.; Ling, T.; Yamada, Y. M. A. "Total synthesis and structural elucidation of azaspiracid-1. Final assignment and total synthesis of the correct structure of azaspiracid-1".
J. Am. Chem. Soc. 2006, 128, 2859-2872.
20. Nicolaou, K. C.*; Chen, D. Y.; Li, Y.; Uesaka, N.; Petriovic, G.; Koftis, T. V.; Bernal, F.; Frederick, M. O.; Govindasamy, M.; Ling, T.; Pihko, P. M.; Tang, W.; Vyskocil, S. "Total synthesis and structural elucidation of azaspiracid-1. Synthesis-based analysis of originally proposed structures and indication of their non-identiy to the natural product".
J. Am. Chem. Soc. 2006, 128, 2258-2267.
19. Nicolaou, K. C.*; Tang, W.; Dagneau P.; Faraoni, R. "A catalytic asymmetric three-component 1,4-addition/aldol reaction: Enantioselective synthesis of the spirocyclic system of vannusal A".
Angew. Chem., Int. Ed. 2005, 44, 3874-3879.
18. Nicolaou, K. C.*; Koftis, T. V.; Vyskocil, S.; Petriovic, G.; Ling, T.; Yamada, Y. M. A.; Tang, W.; Frederick, M. O. "Structural revision and total synthesis of Azaspiracid-1, part 2: Definition of the ABCD domain and total synthesis".
Angew. Chem., Int. Ed. 2004, 43, 4312-4318.
17. Nicolaou, K. C.*; Vyskocil, S.; Koftis, T. V.; Yamada, Y. M. A.; Ling, T.; Chen, D. Y.; Tang, W.; Petriovic, G.; Frederick, M. O.; Li, Y.; Sataki, M. "Structural revision and total synthesis of Azaspircad-1, part 1: Intelligence Gathering and tentative proposal".
Angew. Chem., Int. Ed. 2004, 43, 4318-4324.
16. Liu, D.; Tang, W.; Zhang, X.* "Synthesis of a new class of conformationally rigid phosphino-oxazolines: Highly enantioselective ligands for Ir-catalyzed asymmetric hydrogenation,".
Org. Lett. 2004, 6, 513-516.
15. Tang, W.; Wu, S.; Zhang, X.* "Enantioselective hydrogenation of tetrasubstituted olefines of cyclic β-(acylamino) acrylates".
J. Am. Chem. Soc. 2003, 125, 9570-9571.
14. Tang, W.; Wang, W.; Chi, Y.; Zhang, X.* "A P-chiral-bisphosphepine ligand for practical synthesis of β-aryl β-amino acids via asymmetric hydrogenation". Angew. Chem., Int. Ed. 2003, 42, 3509-3511.
13. Tang, W.; Zhang, X.* "New chiral phosphorous ligands for enantioselective hydrogenation".
Chem. Rev. 2003, 103, 3029-3069.
12. Tang, W.; Liu, D.; Zhang, X.* "Asymmetric hydrogenation of itaconic acid and enol acetate derivatives with the Rh-TangPhos catalyst".
Org. Lett. 2003, 5, 205-207.
11. Tang, W.; Wang, W.; Zhang, X.* "A new class of phospholane-oxazoline ligands for Ir-catalyzed asymmetric hydrogenation".
Angew. Chem., Int. Ed. 2003, 42, 943-946.
10. Ma, D.*; Xia, C.; Jiang, J.; Zhang, J.; Tang, W. "Aromatic nucleophilic substitution or CuI-catalyzed coupling route to Martinellic Acid".
J. Org. Chem. 2003, 68, 442-451.
9. Wu, S.; Wang, W.; Tang, W.; Lin, M.; Zhang, X.* "Highly enantioselective hydrogenation of enol acetates catalyzed by Ru-TunaPhos complexes".
Org. Lett. 2002, 4, 4495-4497.
8. Tang, W.; Zhang, X.* "Highly efficient synthesis of chiral beta-amino acid derivatives via asymmetric hydrogenation".
Org. Lett. 2002, 4, 4159-4161.
7. Korber, K.; Tang, W.; Hu, X.; Zhang, X.* "A practical synthesis of 2-amino-2'-hydroxy-1,1'-binaphthyl (NOBIN)".
Tetrahedron Lett. 2002, 43, 7163-7165.
6. Tang, W.; Chi, Y.; Zhang, X.* "An ortho-substituted BIPHEP ligand and its applications in Rh-catalyzed hydrogenation of cyclic enamides".
Org. Lett. 2002, 4, 1695-1698.
5. Tang, W.; Zhang, X.* "A chiral 1,2-bisphospholane ligand with a novel structural motif: Applications in highly enantioselective Rh-catalyzed hydrogenations". Angew. Chem., Int. Ed. 2002, 41, 1612-1614.
4. Zhou, Y.; Tang, W.; Wang, W.; Li, W.; Zhang, X.* "Highly effective chiral ortho-substituted BINAPO ligands (o-BINAPO): Applications in Ru-catalyzed asymmetric hydrogenations of beta-aryl-substituted beta-(acylamino)acrylates and beta-keto esters".
J. Am. Chem. Soc. 2002, 124, 4952-4953.
3. Tang, W.; Hu, X.; Zhang, X.* "A new chiral ruthenium complex for catalytic asymmetric cyclopropanation".
Tetrahedron Lett. 2002, 43, 3075-3078.
2. Ma, D.*; Tang, W.; Kozikowski, A. P.; Lewin, N. E.; Blumberg, P. M.; "General and stereospecific route to 9-substituted, 8,9-disubstituted, and 9,10-disubstituted analogues of benzolactam-V8".
J. Org. Chem. 1999, 64, 6366-6373.
1. Tang, W.; Ma, D.* "Stereospecific synthesis of 9-substituted benzolactam-V8 from L-tyrosine via orientation transfer of aromatic nitration".
Tetrahedron Lett. 1998, 39, 7369-7372.
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Book Chapters:
4. Wan, F. Yang, H. Tang, W."Chiral Monophosphorus Ligand" of Full Book "Chiral Ligands: Evolution of Ligand Libraries for Asymmetric Catalysis". pa 233-260,2021.Linker
3. Li, K.; Tang, W."Air-stable P-chiral Phosphorus Ligands
for Asymmetric Catalysis and Synthesis" of Full Book "The Strem Chemiker". pa XXX-XXX,2019.Linker
2. Chi, Y.; Tang, W.; Zhang, X. "The other bisphosphine ligands for enantioselective alkene hydrogenation" in Book "Handbook of Homogeneous Hydrogenation". pa 853-882,Editor(s): Prof. Dr. Johannes G. de Vries and Prof. Dr. Cornelis J. Elsevier.
Wiley-VCH, Weinheim, Germany, 2007.
1. Chi, Y.; Tang, W.; Zhang, X. "Rhodium-catalyzed asymmetric hydrogenation". In Book "Modern Rhodium-Catalyzed Organic Reactions" pa 1-31,Editor: P. Andrew Evans, Wiley-VCH, Weinheim, Germany, 2005.
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20. Tang, W.; Fu, W.; Liu, G. "Chiral diphosphine ligand, preparation method, intermediate and application thereof".
Patent No. CN 109293700 A Date Issued: February 1, 2019
19. Tang, W.; Si, T.; Li, B. "Benzo polyaza and phosphole oxygen ligand and complex containing same, preparation method and application".
Patent No. CN 109096338 A Date Issued: December 28, 2018
18. Tang, W.; Chen, D.; Xu, G. "Chirality 1,2-diamine compound and synthetic method thereof".
Patent No. CN 108929268 A Date Issued: December 4, 2018
17. Tang, W.; Jiang, W. "Biaryl diphosphine ligand as well as preparation method and application thereof".
Patent No. CN 107827929 A Date Issued: March 23, 2018
16. Tang, W.; Li, C.; Wan, F. "Metal complex as well as preparation method, application and intermediate thereof".
Patent No. CN 107445999 A Date Issued: December 8, 2017
15. Tang, W.; Zhao, G.; Hu, N. "Transition metal complexes and preparation of chiral α-amino boronic esters".
Patent No. CN 106146543 A Date Issued: November 23, 2016
14. Tang, W.; Huang, L.; Zhu, J. "Aryl substituted alcohols and synthetic methods of escitalopram".
Patent No. CN 105732249 A Date Issued: July 6, 2016
13. Tang, W.; Li, C. "Addressing the Challenging Issues in Crossing-Couplings by Ligand Design".
Patent No. CN 104650145 A Date Issued: May 27, 2015
12. Tang, W.; Liu, G. "Chiral phosphine ligand, metal catalyst comprising the chiral phosphine ligand and their application".
Patent No. CN 103087105 Date Issued: May 8, 2013
11. Schnaubelt, J.; Tang, W. "Method for stereoselective synthesis of 1,4-protected 9-hydroxy-5-oxo-1,4-diaza-spiro[5.5]undecanes".
Patent No. WO 2013117568 Date Issued: Aug 15, 2013
10. Haddad, N.; Qu, B.; Rodriguez, S.; Senanayake, C. H.; Tang, W.(as core maker); Wei, X.; Yee, N. K. "Monophosphorus ligands and their use in cross-coupling reactions".
Patent No. WO 2011126917 Date Issued: Oct 13, 2011
9. Qu, B.; Senanayake, C. H.; Tang, W.(as core maker); Wei, X.; Yee, N. K. "Novel chiral phosphorus ligands".
Patent No. WO 2011056737 Date Issued: May 12, 2011
8. Li, W.; De Croos, P.; Fandrick, K. R.; Gao, J. J.; Haddad, N.; Lu, Z.; Qu, B.; Rodriguez, S.; Senanayake, C. H.; Zhang, Y.; Tang, W. "A process for the preparation of quinoline derivatives for use as HIV integrase inhibitors".
Patent No. WO 2012138670 Date Issued: Oct 11, 2012
7. Patel, N. D.; Senanayake, C. H.; Tang, W.; Wei, X.; Yee, N. K. "Process for preparation of alkoxybromochloroarylquinolines from alkoxydichloroquinolines". Patent No. WO 2010129451 Date Issued: Nov 11, 2010
6. Haddad, N.; Krishnamurthy, D.; Reeves, D. C.; Senanayake, C. H.; Tang, W.; Yee, N. K. "Process for preparation of (S)-3-[4-(benzyloxy)-3,5-dimethylphenyl]-2-[4-(2-oxo- 4,5-dihydro-1H-benzo[d][1,3]diazepin-3(2H)-yl)piperidine-1-carbonyloxy]propanoic aci and related compounds".
Patent No. WO 2010048138 Date Issued: Apr 29, 2010
5. Han, Z.; Kai, G.; Krishnamurthy, D.; Matthes, Burkhard.; Nar, H.; Priepke, H.; Schuler-Metz, A.; Senanayake, C. H.; Sieger, P.; Tang, W.; Wienen, W.; Xu, Y.; Yee, N. K. "Synthesis of 3-aminotetrahydrofuran-3-carboxylic acid derivatives for use as medicaments".
Patent No. WO 2008080891 Date Issued: Jul 10, 2008
4. Wang, X.; Sun, X.; Zhang, L.; Tang, W.; Krishanmurthy D.; Senanayake, C. H.; Han, Z. "Processes for the preparation of glucopyranosyl-substituted benzyl or benzene derivatives".
Patent No. WO 2006120208 Date Issued: Nov 16, 2006
3. Xumu, Z.; Tang, W. "Preparation of chiral cyclic amino acids and derivatives".
Patent No. US 2004242889 Date Issued: Dec 2, 2004
2. Xumu, Z.; Tang, W. "P-Chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions".
Patent No. US 2004229846 Date Issued: Nov 18, 2004
1. Xumu, Z.; Tang, W. "P-Chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions".
Patent No. WO 2003042135 Date Issued: May 22, 2003
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